Preheat oven to 350°F, with the rack in the center.
Spray the sides and bottom of two 8" round cake pans well with nonstick spray. Place parchment rounds (or cut parchment paper to fit) on the bottoms and spray those as well.
cooking spray
Sift the dry ingredients—flour, sugar, cocoa powder, baking soda, and salt—together in a mixing bowl. (This is especially important for cocoa powder, which can clump.)
3 cups all-purpose flour, 2 cups granulated sugar, 1/2 cup unsweetened cocoa powder, 2 tsps. baking soda, 1 tsp. table salt
In a large, pourable measuring cup, combine the water, oil, vinegar, instant coffee, and vanilla. Add to the dry ingredients and whisk just until combined—some lumps are okay. Do not overmix. Divide the batter among the pans (about 3 cups in each), then bake until a toothpick inserted in the center comes out clean, about 35 minutes.
2 cups hot water, 3/4 cups vegetable oil, 2 tbsps. white vinegar, 1 tbsp. instant coffee granules, 1 tbsp. vanilla extract
Cool cakes for 20 minutes on a rack, then invert them onto the rack. Leave cakes upside down to cool completely (this helps flatten domed cakes), then frost.